Enhanced Molecular Spin-Photon Coupling at Superconducting Nanoconstrictions

Ignacio Gimeno*, Wenzel Kersten*, María C. Pallarés*, Pablo Hermosilla, Maria Jose Martinez-Perez, Mark D. Jenkins, Andreas Angerer, Carlos Sánchez-Azqueta, David Zueco, Johannes Majer, Anabel Lostao, and Fernando Luis. Enhanced Molecular Spin-Photon Coupling at Superconducting Nanoconstrictions. ACS Nano 2020 14 (7), 8707-8715

We combine top-down and bottom-up nanolithography to optimize the coupling of small molecular spin ensembles to 1.4 GHz on-chip superconducting resonators. Nanoscopic constrictions, fabricated with a focused ion beam at the central transmission line, locally concentrate the microwave magnetic field. Drops of free-radical molecules have been deposited from solution onto the circuits. For the smallest ones, the molecules were delivered at the relevant circuit areas by means of an atomic force microscope. The number of spins Neff effectively coupled to each device was accurately determined combining Scanning Electron and Atomic Force Microscopies. The collective spin-photon coupling constant has been determined for samples with Neff ranging between 2 × 106 and 1012 spins, and for temperatures down to 44 mK. The results show the well-known collective enhancement of the coupling proportional to the square root of Neff. The average coupling of individual spins is enhanced by more than four orders of magnitude (from 4 mHz up to above 180 Hz) when the transmission line width is reduced from 400 microns down to 42 nm, and reaches maximum values near 1 kHz for molecules located on the smallest nanoconstrictions.

Impact factor: